{"id":1754,"date":"2024-09-20T14:46:56","date_gmt":"2024-09-20T06:46:56","guid":{"rendered":"https:\/\/www.dmdee.org\/archives\/1754"},"modified":"2024-09-20T14:46:56","modified_gmt":"2024-09-20T06:46:56","slug":"%e6%a9%a1%e8%83%b6%e6%b7%bb%e5%8a%a0%e5%89%82%e4%ba%8c%e6%9c%88%e6%a1%82%e9%85%b8%e4%ba%8c%e4%b8%81%e5%9f%ba%e9%94%a1%e7%9a%84%e5%88%b6%e5%a4%87%e6%96%b9%e6%b3%95%e5%8f%8a%e8%b4%a8%e9%87%8f%e6%8e%a7","status":"publish","type":"post","link":"https:\/\/www.dmdee.org\/archives\/1754","title":{"rendered":"\u6a61\u80f6\u6dfb\u52a0\u5242\u4e8c\u6708\u6842\u9178\u4e8c\u4e01\u57fa\u9521\u7684\u5236\u5907\u65b9\u6cd5\u53ca\u8d28\u91cf\u63a7\u5236"},"content":{"rendered":"
\u4e8c\u6708\u6842\u9178\u4e8c\u4e01\u57fa\u9521\uff08dibutyltin dilaurate, DBTDL\uff09\u4f5c\u4e3a\u4e00\u79cd\u9ad8\u6548\u7684\u50ac\u5316\u5242\u548c\u7a33\u5b9a\u5242\uff0c\u5728\u6a61\u80f6\u5de5\u4e1a\u4e2d\u6709\u7740\u5e7f\u6cdb\u7684\u5e94\u7528\u3002\u672c\u6587\u5c06\u8be6\u7ec6\u4ecb\u7ecdDBTDL\u7684\u5236\u5907\u65b9\u6cd5\u53ca\u5176\u8d28\u91cf\u63a7\u5236\u63aa\u65bd\uff0c\u4ee5\u786e\u4fdd\u5176\u5728\u6a61\u80f6\u6dfb\u52a0\u5242\u4e2d\u7684\u6027\u80fd\u548c\u5b89\u5168\u6027\u3002<\/p>\n
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C8H17COOH+Bu2SnO\u2192Bu2Sn(OCOCH11H23)2+H2O\\text{C}_8\\text{H}_{17}\\text{COOH} + \\text{Bu}_2\\text{SnO} \\rightarrow \\text{Bu}_2\\text{Sn}(\\text{OCOCH}_{11}\\text{H}_{23})_2 + \\text{H}_2\\text{O}C<\/span><\/span>8<\/span><\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>H<\/span><\/span>17<\/span><\/span><\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>COOH<\/span><\/span>+<\/span><\/span>Bu<\/span><\/span>2<\/span><\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>SnO<\/span><\/span>\u2192<\/span><\/span>Bu<\/span><\/span>2<\/span><\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>Sn<\/span><\/span>(<\/span>OCOCH<\/span><\/span>11<\/span><\/span><\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>H<\/span><\/span>23<\/span><\/span><\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>)<\/span>2<\/span><\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>+<\/span><\/span>H<\/span><\/span>2<\/span><\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>O<\/span><\/span><\/span><\/span><\/p>\n<\/li>\n<\/ul>\n<\/li>\n \u4e3a\u4e86\u786e\u4fdd\u4e8c\u6708\u6842\u9178\u4e8c\u4e01\u57fa\u9521\u7684\u8d28\u91cf\u548c\u6027\u80fd\uff0c\u9700\u8981\u91c7\u53d6\u4e00\u7cfb\u5217\u4e25\u683c\u7684\u8d28\u91cf\u63a7\u5236\u63aa\u65bd\u3002<\/p>\n \u901a\u8fc7\u5bf9\u4e8c\u6708\u6842\u9178\u4e8c\u4e01\u57fa\u9521\u7684\u5236\u5907\u65b9\u6cd5\u53ca\u5176\u8d28\u91cf\u63a7\u5236\u63aa\u65bd\u7684\u8be6\u7ec6\u63a2\u8ba8\uff0c\u6211\u4eec\u5f97\u51fa\u4ee5\u4e0b\u7ed3\u8bba\uff1a<\/p>\n \u672a\u6765\u7684\u7814\u7a76\u65b9\u5411\u5c06\u66f4\u52a0\u6ce8\u91cd\u5f00\u53d1\u66f4\u52a0\u73af\u4fdd\u3001\u9ad8\u6548\u7684\u5236\u5907\u65b9\u6cd5\uff0c\u51cf\u5c11\u5bf9\u73af\u5883\u7684\u5f71\u54cd\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u8fdb\u4e00\u6b65\u4f18\u5316DBTDL\u7684\u4f7f\u7528\u6761\u4ef6\uff0c\u5982\u6dfb\u52a0\u91cf\u3001\u53cd\u5e94\u6e29\u5ea6\u7b49\uff0c\u53ef\u4ee5\u8fdb\u4e00\u6b65\u63d0\u9ad8\u5176\u5728\u6a61\u80f6\u5de5\u4e1a\u4e2d\u7684\u5e94\u7528\u6548\u679c\u3002<\/p>\n \u672c\u6587\u63d0\u4f9b\u4e86\u5bf9\u4e8c\u6708\u6842\u9178\u4e8c\u4e01\u57fa\u9521\u5728\u6a61\u80f6\u6dfb\u52a0\u5242\u4e2d\u7684\u5236\u5907\u65b9\u6cd5\u53ca\u8d28\u91cf\u63a7\u5236\u63aa\u65bd\u7684\u8be6\u7ec6\u4ecb\u7ecd\u3002\u5bf9\u4e8e\u66f4\u6df1\u5165\u7684\u7814\u7a76\uff0c\u5efa\u8bae\u67e5\u9605\u76f8\u5173\u9886\u57df\u7684\u65b0\u79d1\u7814\u6587\u732e\uff0c\u4ee5\u4fbf\u83b7\u53d6\u65b0\u7684\u7814\u7a76\u8fdb\u5c55\u548c\u6570\u636e\u3002<\/p>\n \u6269\u5c55\u9605\u8bfb\uff1a<\/p>\n cyclohexylamine<\/u><\/a><\/p>\n Tetrachloroethylene Perchloroethylene CAS:127-18-4<\/u><\/a><\/p>\n NT CAT DMDEE<\/u><\/a><\/p>\n NT CAT PC-5<\/u><\/a><\/p>\n N-Methylmorpholine<\/u><\/a><\/p>\n 4-Formylmorpholine<\/u><\/a><\/p>\n Toyocat TE tertiary amine catalyst Tosoh<\/u><\/a><\/p>\n Toyocat RX5 catalyst trimethylhydroxyethyl ethylenediamine Tosoh<\/u><\/a><\/p>\n\n
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\u56db\u3001\u7ed3\u8bba\u4e0e\u5c55\u671b<\/h4>\n
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