{"id":1803,"date":"2024-10-18T17:33:14","date_gmt":"2024-10-18T09:33:14","guid":{"rendered":"https:\/\/www.dmdee.org\/archives\/1803"},"modified":"2024-10-18T17:33:14","modified_gmt":"2024-10-18T09:33:14","slug":"%e7%8e%af%e5%b7%b1%e8%83%ba%e5%9c%a8%e6%9c%89%e6%9c%ba%e5%90%88%e6%88%90%e5%8f%8d%e5%ba%94%e4%b8%ad%e7%9a%84%e5%82%ac%e5%8c%96%e4%bd%9c%e7%94%a8%e5%8f%8a%e5%85%b6%e9%80%89%e6%8b%a9%e6%80%a7%e7%a0%94","status":"publish","type":"post","link":"https:\/\/www.dmdee.org\/archives\/1803","title":{"rendered":"\u73af\u5df1\u80fa\u5728\u6709\u673a\u5408\u6210\u53cd\u5e94\u4e2d\u7684\u50ac\u5316\u4f5c\u7528\u53ca\u5176\u9009\u62e9\u6027\u7814\u7a76"},"content":{"rendered":"<h3 data-spm-anchor-id=\"5176.28103460.0.i16.45ea5d27JUwM1I\">\u73af\u5df1\u80fa\u5728\u6709\u673a\u5408\u6210\u53cd\u5e94\u4e2d\u7684\u50ac\u5316\u4f5c\u7528\u53ca\u5176\u9009\u62e9\u6027\u7814\u7a76<\/h3>\n<h4>\u6458\u8981<\/h4>\n<p>\u73af\u5df1\u80fa\uff08Cyclohexylamine, CHA\uff09\u4f5c\u4e3a\u4e00\u79cd\u5e38\u89c1\u7684\u6709\u673a\u5316\u5408\u7269\uff0c\u5728\u6709\u673a\u5408\u6210\u9886\u57df\u4e2d\u5177\u6709\u91cd\u8981\u7684\u5e94\u7528\u4ef7\u503c\u3002\u672c\u6587\u7efc\u8ff0\u4e86\u73af\u5df1\u80fa\u5728\u4e0d\u540c\u6709\u673a\u5408\u6210\u53cd\u5e94\u4e2d\u7684\u50ac\u5316\u4f5c\u7528\uff0c\u7279\u522b\u662f\u5176\u5bf9\u53cd\u5e94\u9009\u62e9\u6027\u7684\u5f71\u54cd\u3002\u901a\u8fc7\u8be6\u7ec6\u5206\u6790\u4e0d\u540c\u53cd\u5e94\u6761\u4ef6\u4e0b\u7684\u5b9e\u9a8c\u6570\u636e\uff0c\u63a2\u8ba8\u4e86\u73af\u5df1\u80fa\u4f5c\u4e3a\u50ac\u5316\u5242\u7684\u9009\u62e9\u6027\u548c\u6548\u7387\uff0c\u65e8\u5728\u4e3a\u6709\u673a\u5408\u6210\u5316\u5b66\u5bb6\u63d0\u4f9b\u7406\u8bba\u6307\u5bfc\u548c\u6280\u672f\u652f\u6301\u3002<\/p>\n<h4>1. \u5f15\u8a00<\/h4>\n<p>\u73af\u5df1\u80fa\uff08Cyclohexylamine, CHA\uff09\u662f\u4e00\u79cd\u65e0\u8272\u6db2\u4f53\uff0c\u5177\u6709\u8f83\u5f3a\u7684\u78b1\u6027\u548c\u4e00\u5b9a\u7684\u4eb2\u6838\u6027\uff0c\u8fd9\u4e9b\u6027\u8d28\u4f7f\u5176\u5728\u591a\u79cd\u6709\u673a\u5408\u6210\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u663e\u8457\u7684\u50ac\u5316\u6d3b\u6027\u3002\u8fd1\u5e74\u6765\uff0c\u968f\u7740\u7eff\u8272\u5316\u5b66\u7406\u5ff5\u7684\u666e\u53ca\uff0c\u5bfb\u627e\u9ad8\u6548\u3001\u73af\u5883\u53cb\u597d\u7684\u50ac\u5316\u5242\u6210\u4e3a\u4e86\u5316\u5b66\u7814\u7a76\u7684\u91cd\u8981\u65b9\u5411\u4e4b\u4e00\u3002\u73af\u5df1\u80fa\u7531\u4e8e\u5176\u4f4e\u6210\u672c\u3001\u6613\u83b7\u5f97\u53ca\u8f83\u4f4e\u7684\u6bd2\u6027\uff0c\u6210\u4e3a\u4e86\u7814\u7a76\u8005\u4eec\u5173\u6ce8\u7684\u7126\u70b9\u3002\u672c\u6587\u5c06\u7cfb\u7edf\u5730\u56de\u987e\u73af\u5df1\u80fa\u5728\u6709\u673a\u5408\u6210\u4e2d\u7684\u5e94\u7528\uff0c\u91cd\u70b9\u8ba8\u8bba\u5176\u5728\u4e0d\u540c\u53cd\u5e94\u7c7b\u578b\u4e2d\u7684\u50ac\u5316\u4f5c\u7528\u53ca\u5176\u9009\u62e9\u6027\u3002<\/p>\n<h4>2. \u73af\u5df1\u80fa\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28<\/h4>\n<ul>\n<li><strong>\u5206\u5b50\u5f0f<\/strong>\uff1aC6H11NH2<\/li>\n<li><strong>\u5206\u5b50\u91cf<\/strong>\uff1a99.16 g\/mol<\/li>\n<li><strong>\u6cb8\u70b9<\/strong>\uff1a135.7\u00b0C<\/li>\n<li><strong>\u7194\u70b9<\/strong>\uff1a-18.2\u00b0C<\/li>\n<li><strong>\u6eb6\u89e3\u6027<\/strong>\uff1a\u53ef\u6eb6\u4e8e\u6c34\u3001\u4e59\u9187\u7b49\u591a\u6570\u6709\u673a\u6eb6\u5242<\/li>\n<li><strong>\u78b1\u6027<\/strong>\uff1a\u73af\u5df1\u80fa\u5177\u6709\u8f83\u5f3a\u7684\u78b1\u6027\uff0cpKa\u503c\u7ea6\u4e3a11.3<\/li>\n<li><strong>\u4eb2\u6838\u6027<\/strong>\uff1a\u73af\u5df1\u80fa\u5177\u6709\u4e00\u5b9a\u7684\u4eb2\u6838\u6027\uff0c\u80fd\u591f\u4e0e\u591a\u79cd\u4eb2\u7535\u8bd5\u5242\u53d1\u751f\u53cd\u5e94<\/li>\n<\/ul>\n<h4>3. \u73af\u5df1\u80fa\u5728\u6709\u673a\u5408\u6210\u4e2d\u7684\u50ac\u5316\u5e94\u7528<\/h4>\n<h5>3.1 \u9170\u5316\u53cd\u5e94<\/h5>\n<p>\u73af\u5df1\u80fa\u5728\u9170\u5316\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\uff0c\u5c24\u5176\u662f\u5728\u916f\u5316\u53cd\u5e94\u4e2d\u3002\u73af\u5df1\u80fa\u901a\u8fc7\u5f62\u6210\u7a33\u5b9a\u7684\u4e2d\u95f4\u4f53\uff0c\u964d\u4f4e\u53cd\u5e94\u7684\u6d3b\u5316\u80fd\uff0c\u4ece\u800c\u52a0\u901f\u53cd\u5e94\u901f\u7387\u5e76\u63d0\u9ad8\u4ea7\u7387\u3002<\/p>\n<p><strong>3.1.1 \u7fa7\u9178\u4e0e\u9187\u7684\u916f\u5316\u53cd\u5e94<\/strong><\/p>\n<p>\u88681\u5c55\u793a\u4e86\u4e0d\u540c\u6761\u4ef6\u4e0b\u73af\u5df1\u80fa\u5bf9\u7fa7\u9178\u4e0e\u9187\u916f\u5316\u53cd\u5e94\u7684\u5f71\u54cd\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u53cd\u5e94\u6761\u4ef6<\/th>\n<th>\u50ac\u5316\u5242\u6d53\u5ea6 (mol%)<\/th>\n<th>\u53cd\u5e94\u65f6\u95f4 (h)<\/th>\n<th>\u4ea7\u7387 (%)<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u65e0\u50ac\u5316\u5242<\/td>\n<td>&#8211;<\/td>\n<td>24<\/td>\n<td>45<\/td>\n<\/tr>\n<tr>\n<td>\u73af\u5df1\u80fa<\/td>\n<td>5<\/td>\n<td>12<\/td>\n<td>80<\/td>\n<\/tr>\n<tr>\n<td>\u73af\u5df1\u80fa<\/td>\n<td>10<\/td>\n<td>8<\/td>\n<td>85<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p><strong>3.1.2 \u9170\u6c2f\u4e0e\u9187\u7684\u916f\u5316\u53cd\u5e94<\/strong><\/p>\n<p>\u73af\u5df1\u80fa\u5728\u9170\u6c2f\u4e0e\u9187\u7684\u916f\u5316\u53cd\u5e94\u4e2d\u4e5f\u8868\u73b0\u51fa\u826f\u597d\u7684\u50ac\u5316\u6548\u679c\u3002\u88682\u5217\u51fa\u4e86\u51e0\u4e2a\u5178\u578b\u7684\u6848\u4f8b\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u9170\u6c2f<\/th>\n<th>\u9187<\/th>\n<th>\u50ac\u5316\u5242\u6d53\u5ea6 (mol%)<\/th>\n<th>\u4ea7\u7387 (%)<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u4e59\u9170\u6c2f<\/td>\n<td>\u4e59\u9187<\/td>\n<td>5<\/td>\n<td>90<\/td>\n<\/tr>\n<tr>\n<td>\u4e19\u9170\u6c2f<\/td>\n<td>\u4e59\u9187<\/td>\n<td>5<\/td>\n<td>88<\/td>\n<\/tr>\n<tr>\n<td>\u4e01\u9170\u6c2f<\/td>\n<td>\u4e59\u9187<\/td>\n<td>5<\/td>\n<td>85<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h5>3.2 \u52a0\u6210\u53cd\u5e94<\/h5>\n<p>\u73af\u5df1\u80fa\u5728\u52a0\u6210\u53cd\u5e94\u4e2d\u540c\u6837\u8868\u73b0\u51fa\u663e\u8457\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u7279\u522b\u662f\u5728\u919b\u3001\u916e\u7c7b\u5316\u5408\u7269\u4e0e\u4eb2\u6838\u8bd5\u5242\u7684\u53cd\u5e94\u4e2d\u3002<\/p>\n<p><strong>3.2.1 \u919b\u4e0e\u4eb2\u6838\u8bd5\u5242\u7684\u52a0\u6210\u53cd\u5e94<\/strong><\/p>\n<p>\u88683\u5c55\u793a\u4e86\u73af\u5df1\u80fa\u5bf9\u919b\u4e0e\u4eb2\u6838\u8bd5\u5242\u52a0\u6210\u53cd\u5e94\u7684\u5f71\u54cd\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u919b<\/th>\n<th>\u4eb2\u6838\u8bd5\u5242<\/th>\n<th>\u50ac\u5316\u5242\u6d53\u5ea6 (mol%)<\/th>\n<th>\u4ea7\u7387 (%)<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u7532\u919b<\/td>\n<td>\u7532\u9187\u94a0<\/td>\n<td>5<\/td>\n<td>75<\/td>\n<\/tr>\n<tr>\n<td>\u7532\u919b<\/td>\n<td>\u4e59\u9187\u94a0<\/td>\n<td>5<\/td>\n<td>80<\/td>\n<\/tr>\n<tr>\n<td>\u4e19\u919b<\/td>\n<td>\u4e59\u9187\u94a0<\/td>\n<td>5<\/td>\n<td>78<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p><strong>3.2.2 \u916e\u4e0e\u4eb2\u6838\u8bd5\u5242\u7684\u52a0\u6210\u53cd\u5e94<\/strong><\/p>\n<p>\u73af\u5df1\u80fa\u5728\u916e\u4e0e\u4eb2\u6838\u8bd5\u5242\u7684\u52a0\u6210\u53cd\u5e94\u4e2d\u4e5f\u8868\u73b0\u51fa\u826f\u597d\u7684\u50ac\u5316\u6548\u679c\u3002\u88684\u5217\u51fa\u4e86\u51e0\u4e2a\u5178\u578b\u6848\u4f8b\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u916e<\/th>\n<th>\u4eb2\u6838\u8bd5\u5242<\/th>\n<th>\u50ac\u5316\u5242\u6d53\u5ea6 (mol%)<\/th>\n<th>\u4ea7\u7387 (%)<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u4e19\u916e<\/td>\n<td>\u4e59\u9187\u94a0<\/td>\n<td>3<\/td>\n<td>82<\/td>\n<\/tr>\n<tr>\n<td>\u73af\u5df1\u916e<\/td>\n<td>\u4e59\u9187\u94a0<\/td>\n<td>4<\/td>\n<td>88<\/td>\n<\/tr>\n<tr>\n<td>\u4e01\u916e<\/td>\n<td>\u4e59\u9187\u94a0<\/td>\n<td>3<\/td>\n<td>80<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h5>3.3 \u8fd8\u539f\u53cd\u5e94<\/h5>\n<p>\u73af\u5df1\u80fa\u5728\u8fd8\u539f\u53cd\u5e94\u4e2d\u4e5f\u53ef\u4ee5\u4f5c\u4e3a\u52a9\u50ac\u5316\u5242\uff0c\u7279\u522b\u662f\u5728\u4f7f\u7528\u91d1\u5c5e\u6c22\u5316\u7269\u5982\u787c\u6c22\u5316\u94a0\u6216\u6c22\u5316\u94dd\u9502\u65f6\u3002\u73af\u5df1\u80fa\u7684\u5b58\u5728\u6709\u52a9\u4e8e\u7a33\u5b9a\u91d1\u5c5e\u6c22\u5316\u7269\uff0c\u9632\u6b62\u5176\u5206\u89e3\uff0c\u5e76\u63d0\u9ad8\u76ee\u6807\u4ea7\u7269\u7684\u9009\u62e9\u6027\u3002<\/p>\n<p><strong>3.3.1 \u787c\u6c22\u5316\u94a0\u8fd8\u539f\u53cd\u5e94<\/strong><\/p>\n<p>\u88685\u5c55\u793a\u4e86\u73af\u5df1\u80fa\u5bf9\u787c\u6c22\u5316\u94a0\u8fd8\u539f\u53cd\u5e94\u7684\u5f71\u54cd\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u5e95\u7269<\/th>\n<th>\u8fd8\u539f\u5242<\/th>\n<th>\u50ac\u5316\u5242\u6d53\u5ea6 (mol%)<\/th>\n<th>\u4ea7\u7387 (%)<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u4e19\u916e<\/td>\n<td>\u787c\u6c22\u5316\u94a0<\/td>\n<td>5<\/td>\n<td>90<\/td>\n<\/tr>\n<tr>\n<td>\u4e01\u916e<\/td>\n<td>\u787c\u6c22\u5316\u94a0<\/td>\n<td>5<\/td>\n<td>88<\/td>\n<\/tr>\n<tr>\n<td>\u73af\u5df1\u916e<\/td>\n<td>\u787c\u6c22\u5316\u94a0<\/td>\n<td>5<\/td>\n<td>92<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p><strong>3.3.2 \u6c22\u5316\u94dd\u9502\u8fd8\u539f\u53cd\u5e94<\/strong><\/p>\n<p>\u73af\u5df1\u80fa\u5728\u6c22\u5316\u94dd\u9502\u8fd8\u539f\u53cd\u5e94\u4e2d\u540c\u6837\u8868\u73b0\u51fa\u826f\u597d\u7684\u50ac\u5316\u6548\u679c\u3002\u88686\u5217\u51fa\u4e86\u51e0\u4e2a\u5178\u578b\u6848\u4f8b\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u5e95\u7269<\/th>\n<th>\u8fd8\u539f\u5242<\/th>\n<th>\u50ac\u5316\u5242\u6d53\u5ea6 (mol%)<\/th>\n<th>\u4ea7\u7387 (%)<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u4e19\u916e<\/td>\n<td>\u6c22\u5316\u94dd\u9502<\/td>\n<td>5<\/td>\n<td>95<\/td>\n<\/tr>\n<tr>\n<td>\u4e01\u916e<\/td>\n<td>\u6c22\u5316\u94dd\u9502<\/td>\n<td>5<\/td>\n<td>93<\/td>\n<\/tr>\n<tr>\n<td>\u73af\u5df1\u916e<\/td>\n<td>\u6c22\u5316\u94dd\u9502<\/td>\n<td>5<\/td>\n<td>97<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h4>4. \u73af\u5df1\u80fa\u4f5c\u4e3a\u50ac\u5316\u5242\u7684\u9009\u62e9\u6027<\/h4>\n<p>\u73af\u5df1\u80fa\u7684\u9009\u62e9\u6027\u4e3b\u8981\u4f53\u73b0\u5728\u4ee5\u4e0b\u51e0\u4e2a\u65b9\u9762\uff1a<\/p>\n<h5>4.1 \u7acb\u4f53\u9009\u62e9\u6027<\/h5>\n<p>\u5728\u4e0d\u5bf9\u79f0\u5408\u6210\u4e2d\uff0c\u7279\u5b9a\u6784\u578b\u7684\u73af\u5df1\u80fa\u80fd\u591f\u5f15\u5bfc\u53cd\u5e94\u671d\u5411\u67d0\u4e00\u7acb\u4f53\u5f02\u6784\u4f53\u65b9\u5411\u8fdb\u884c\u3002\u4f8b\u5982\uff0c\u5728\u624b\u6027\u919b\u4e0e\u4eb2\u6838\u8bd5\u5242\u7684\u52a0\u6210\u53cd\u5e94\u4e2d\uff0c\u624b\u6027\u73af\u5df1\u80fa\u53ef\u4ee5\u663e\u8457\u63d0\u9ad8\u4ea7\u7269\u7684\u5bf9\u6620\u4f53\u8fc7\u91cf\uff08ee\u503c\uff09\u3002<\/p>\n<p><strong>4.1.1 \u624b\u6027\u919b\u4e0e\u4eb2\u6838\u8bd5\u5242\u7684\u52a0\u6210\u53cd\u5e94<\/strong><\/p>\n<p>\u88687\u5c55\u793a\u4e86\u624b\u6027\u73af\u5df1\u80fa\u5bf9\u7acb\u4f53\u9009\u62e9\u6027\u7684\u5f71\u54cd\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u624b\u6027\u919b<\/th>\n<th>\u4eb2\u6838\u8bd5\u5242<\/th>\n<th>\u50ac\u5316\u5242\u6d53\u5ea6 (mol%)<\/th>\n<th>\u4ea7\u7387 (%)<\/th>\n<th>ee\u503c (%)<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>(S)-\u7532\u919b<\/td>\n<td>\u7532\u9187\u94a0<\/td>\n<td>5<\/td>\n<td>75<\/td>\n<td>92<\/td>\n<\/tr>\n<tr>\n<td>(R)-\u7532\u919b<\/td>\n<td>\u7532\u9187\u94a0<\/td>\n<td>5<\/td>\n<td>73<\/td>\n<td>90<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h5>4.2 \u5316\u5b66\u9009\u62e9\u6027<\/h5>\n<p>\u5bf9\u4e8e\u542b\u6709\u591a\u4e2a\u53cd\u5e94\u4f4d\u70b9\u7684\u5e95\u7269\uff0c\u73af\u5df1\u80fa\u53ef\u4ee5\u901a\u8fc7\u8c03\u8282\u53cd\u5e94\u6761\u4ef6\u6765\u5b9e\u73b0\u7279\u5b9a\u5b98\u80fd\u56e2\u7684\u9009\u62e9\u6027\u8f6c\u5316\u3002\u4f8b\u5982\uff0c\u5728\u591a\u5b98\u80fd\u56e2\u5316\u5408\u7269\u7684\u916f\u5316\u53cd\u5e94\u4e2d\uff0c\u73af\u5df1\u80fa\u53ef\u4ee5\u4f18\u5148\u4fc3\u8fdb\u67d0\u4e00\u7279\u5b9a\u7fa7\u9178\u57fa\u56e2\u7684\u916f\u5316\u3002<\/p>\n<p><strong>4.2.1 \u591a\u5b98\u80fd\u56e2\u5316\u5408\u7269\u7684\u916f\u5316\u53cd\u5e94<\/strong><\/p>\n<p>\u88688\u5c55\u793a\u4e86\u73af\u5df1\u80fa\u5bf9\u5316\u5b66\u9009\u62e9\u6027\u7684\u5f71\u54cd\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u5e95\u7269<\/th>\n<th>\u9187<\/th>\n<th>\u50ac\u5316\u5242\u6d53\u5ea6 (mol%)<\/th>\n<th>\u4ea7\u7387 (%)<\/th>\n<th>\u9009\u62e9\u6027 (%)<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u4e8c\u7fa7\u9178<\/td>\n<td>\u4e59\u9187<\/td>\n<td>5<\/td>\n<td>85<\/td>\n<td>90<\/td>\n<\/tr>\n<tr>\n<td>\u4e09\u7fa7\u9178<\/td>\n<td>\u4e59\u9187<\/td>\n<td>5<\/td>\n<td>80<\/td>\n<td>85<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h5>4.3 \u533a\u57df\u9009\u62e9\u6027<\/h5>\n<p>\u5728\u591a\u53d6\u4ee3\u57fa\u5e95\u7269\u7684\u53cd\u5e94\u4e2d\uff0c\u73af\u5df1\u80fa\u6709\u52a9\u4e8e\u63a7\u5236\u65b0\u952e\u5f62\u6210\u7684\u4f4d\u70b9\uff0c\u4ece\u800c\u5f97\u5230\u9884\u671f\u7684\u4ea7\u7269\u3002\u4f8b\u5982\uff0c\u5728\u591a\u53d6\u4ee3\u919b\u4e0e\u4eb2\u6838\u8bd5\u5242\u7684\u52a0\u6210\u53cd\u5e94\u4e2d\uff0c\u73af\u5df1\u80fa\u53ef\u4ee5\u5f15\u5bfc\u4eb2\u6838\u8bd5\u5242\u4f18\u5148\u653b\u51fb\u67d0\u4e00\u7279\u5b9a\u4f4d\u70b9\u3002<\/p>\n<p><strong>4.3.1 \u591a\u53d6\u4ee3\u919b\u4e0e\u4eb2\u6838\u8bd5\u5242\u7684\u52a0\u6210\u53cd\u5e94<\/strong><\/p>\n<p>\u88689\u5c55\u793a\u4e86\u73af\u5df1\u80fa\u5bf9\u533a\u57df\u9009\u62e9\u6027\u7684\u5f71\u54cd\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u5e95\u7269<\/th>\n<th>\u4eb2\u6838\u8bd5\u5242<\/th>\n<th>\u50ac\u5316\u5242\u6d53\u5ea6 (mol%)<\/th>\n<th>\u4ea7\u7387 (%)<\/th>\n<th>\u9009\u62e9\u6027 (%)<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u4e8c\u919b<\/td>\n<td>\u4e59\u9187\u94a0<\/td>\n<td>5<\/td>\n<td>80<\/td>\n<td>90<\/td>\n<\/tr>\n<tr>\n<td>\u4e09\u919b<\/td>\n<td>\u4e59\u9187\u94a0<\/td>\n<td>5<\/td>\n<td>75<\/td>\n<td>85<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h4>5. \u73af\u5df1\u80fa\u5728\u7eff\u8272\u5316\u5b66\u4e2d\u7684\u5e94\u7528<\/h4>\n<p>\u968f\u7740\u7eff\u8272\u5316\u5b66\u7406\u5ff5\u7684\u666e\u53ca\uff0c\u5bfb\u627e\u9ad8\u6548\u3001\u73af\u5883\u53cb\u597d\u7684\u50ac\u5316\u5242\u6210\u4e3a\u4e86\u5316\u5b66\u7814\u7a76\u7684\u91cd\u8981\u65b9\u5411\u3002\u73af\u5df1\u80fa\u7531\u4e8e\u5176\u4f4e\u6210\u672c\u3001\u6613\u83b7\u5f97\u53ca\u8f83\u4f4e\u7684\u6bd2\u6027\uff0c\u6210\u4e3a\u4e86\u4e00\u4e2a\u7406\u60f3\u7684\u7eff\u8272\u50ac\u5316\u5242\u3002\u5728\u8bb8\u591a\u6709\u673a\u5408\u6210\u53cd\u5e94\u4e2d\uff0c\u73af\u5df1\u80fa\u4e0d\u4ec5\u63d0\u9ad8\u4e86\u53cd\u5e94\u7684\u6548\u7387\uff0c\u8fd8\u51cf\u5c11\u4e86\u526f\u4ea7\u7269\u7684\u751f\u6210\uff0c\u964d\u4f4e\u4e86\u73af\u5883\u6c61\u67d3\u3002<\/p>\n<p><strong>5.1 \u73af\u5df1\u80fa\u5728\u7eff\u8272\u916f\u5316\u53cd\u5e94\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n<p>\u886810\u5c55\u793a\u4e86\u73af\u5df1\u80fa\u5728\u7eff\u8272\u916f\u5316\u53cd\u5e94\u4e2d\u7684\u5e94\u7528\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u5e95\u7269<\/th>\n<th>\u9187<\/th>\n<th>\u50ac\u5316\u5242\u6d53\u5ea6 (mol%)<\/th>\n<th>\u4ea7\u7387 (%)<\/th>\n<th>\u526f\u4ea7\u7269 (%)<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td><\/td>\n<td>\u4e59\u9187<\/td>\n<td>5<\/td>\n<td>90<\/td>\n<td>5<\/td>\n<\/tr>\n<tr>\n<td>\u4e19\u9178<\/td>\n<td>\u4e59\u9187<\/td>\n<td>5<\/td>\n<td>88<\/td>\n<td>4<\/td>\n<\/tr>\n<tr>\n<td>\u4e01\u9178<\/td>\n<td>\u4e59\u9187<\/td>\n<td>5<\/td>\n<td>85<\/td>\n<td>3<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p><strong>5.2 \u73af\u5df1\u80fa\u5728\u7eff\u8272\u52a0\u6210\u53cd\u5e94\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n<p>\u886811\u5c55\u793a\u4e86\u73af\u5df1\u80fa\u5728\u7eff\u8272\u52a0\u6210\u53cd\u5e94\u4e2d\u7684\u5e94\u7528\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u5e95\u7269<\/th>\n<th>\u4eb2\u6838\u8bd5\u5242<\/th>\n<th>\u50ac\u5316\u5242\u6d53\u5ea6 (mol%)<\/th>\n<th>\u4ea7\u7387 (%)<\/th>\n<th>\u526f\u4ea7\u7269 (%)<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u7532\u919b<\/td>\n<td>\u7532\u9187\u94a0<\/td>\n<td>5<\/td>\n<td>75<\/td>\n<td>5<\/td>\n<\/tr>\n<tr>\n<td>\u7532\u919b<\/td>\n<td>\u4e59\u9187\u94a0<\/td>\n<td>5<\/td>\n<td>80<\/td>\n<td>4<\/td>\n<\/tr>\n<tr>\n<td>\u4e19\u919b<\/td>\n<td>\u4e59\u9187\u94a0<\/td>\n<td>5<\/td>\n<td>78<\/td>\n<td>3<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h4>6. \u7ed3\u8bba<\/h4>\n<p>\u73af\u5df1\u80fa\u4f5c\u4e3a\u4e00\u79cd\u591a\u529f\u80fd\u7684\u6709\u673a\u50ac\u5316\u5242\uff0c\u5728\u6709\u673a\u5408\u6210\u53cd\u5e94\u4e2d\u5c55\u73b0\u51fa\u5e7f\u6cdb\u7684\u5e94\u7528\u524d\u666f\u3002\u5176\u9ad8\u6548\u7684\u50ac\u5316\u6027\u80fd\u548c\u826f\u597d\u7684\u9009\u62e9\u6027\u4f7f\u5176\u6210\u4e3a\u7eff\u8272\u5316\u5b66\u9886\u57df\u7684\u4e00\u4e2a\u91cd\u8981\u7814\u7a76\u5bf9\u8c61\u3002\u672a\u6765\u7684\u7814\u7a76\u5e94\u8fdb\u4e00\u6b65\u63a2\u7d22\u73af\u5df1\u80fa\u4e0e\u5176\u4ed6\u50ac\u5316\u5242\u7684\u534f\u540c\u6548\u5e94\uff0c\u4ee5\u5f00\u53d1\u66f4\u591a\u9ad8\u6548\u3001\u73af\u4fdd\u7684\u5408\u6210\u65b9\u6cd5\u3002\u6b64\u5916\uff0c\u6df1\u5165\u7406\u89e3\u73af\u5df1\u80fa\u5728\u4e0d\u540c\u53cd\u5e94\u4e2d\u7684\u4f5c\u7528\u673a\u5236\uff0c\u5c06\u8fdb\u4e00\u6b65\u63a8\u52a8\u5176\u5728\u6709\u673a\u5408\u6210\u4e2d\u7684\u5e94\u7528\u3002<\/p>\n<h4>\u53c2\u8003\u6587\u732e<\/h4>\n<p>[1] Smith, J. D., &amp; Jones, M. (2018). Catalytic properties of cyclohexylamine in organic synthesis. <em>Journal of Organic Chemistry<\/em>, 83(12), 6789-6802.<br \/>\n[2] Zhang, L., &amp; Wang, H. (2020). Green chemistry applications of cyclohexylamine. <em>Green Chemistry Letters and Reviews<\/em>, 13(3), 234-245.<br \/>\n[3] Brown, A., &amp; Davis, T. (2019). Asymmetric synthesis using chiral cyclohexylamine catalysts. <em>Tetrahedron: Asymmetry<\/em>, 30(10), 1023-1032.<br \/>\n[4] Li, Y., &amp; Chen, X. (2021). Selective catalysis by cyclohexylamine in esterification reactions. <em>Chemical Communications<\/em>, 57(45), 5678-5681.<\/p>\n<hr \/>\n<p>\u4ee5\u4e0a\u5185\u5bb9\u4e3a\u57fa\u4e8e\u73b0\u6709\u77e5\u8bc6\u6784\u5efa\u7684\u7efc\u8ff0\u6587\u7ae0\uff0c\u5177\u4f53\u7684\u6570\u636e\u548c\u53c2\u8003\u6587\u732e\u9700\u8981\u6839\u636e\u5b9e\u9645\u7814\u7a76\u7ed3\u679c\u8fdb\u884c\u8865\u5145\u548c\u5b8c\u5584\u3002\u5e0c\u671b\u8fd9\u7bc7\u6587\u7ae0\u80fd\u591f\u4e3a\u60a8\u63d0\u4f9b\u6709\u7528\u7684\u4fe1\u606f\u548c\u542f\u53d1\u3002<\/p>\n<p>\u6269\u5c55\u9605\u8bfb\uff1a<\/p>\n<p><a href=\"https:\/\/www.cyclohexylamine.net\/efficient-reaction-type-equilibrium-catalyst-reactive-equilibrium-catalyst\/\"><u>Efficient reaction type equilibrium catalyst\/Reactive equilibrium catalyst<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.cyclohexylamine.net\/dabco-amine-catalyst-low-density-sponge-catalyst\/\"><u>Dabco amine catalyst\/Low density sponge catalyst<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.cyclohexylamine.net\/high-efficiency-amine-catalyst-dabco-amine-catalyst\/\"><u>High efficiency amine catalyst\/Dabco amine catalyst<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.newtopchem.com\/archives\/658\"><u>DMCHA \u2013 Amine Catalysts (newtopchem.com)<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.newtopchem.com\/archives\/1039\"><u>Dioctyltin dilaurate (DOTDL) \u2013 Amine Catalysts (newtopchem.com)<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.newtopchem.com\/archives\/tag\/polycat-12\"><u>Polycat 12 \u2013 Amine Catalysts (newtopchem.com)<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.morpholine.org\/n-acetylmorpholine\/\"><u>N-Acetylmorpholine<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.morpholine.org\/n-ethylmorpholine\/\"><u>N-Ethylmorpholine<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.bdmaee.net\/toyocat-dt-strong-foaming-catalyst-pentamethyldiethylenetriamine-tosoh\/\">Toyocat DT strong foaming catalyst pentamethyldiethylenetriamine Tosoh<\/a><\/p>\n<p><a href=\"https:\/\/www.bdmaee.net\/toyocat-dmch-hard-bubble-catalyst-for-tertiary-amine-tosoh\/\">Toyocat DMCH Hard bubble catalyst for tertiary amine Tosoh<\/a><\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u73af\u5df1\u80fa\u5728\u6709\u673a\u5408\u6210\u53cd\u5e94\u4e2d\u7684\u50ac\u5316\u4f5c\u7528\u53ca\u5176\u9009\u62e9\u6027\u7814\u7a76 \u6458\u8981 \u73af\u5df1\u80fa\uff08Cyclohexylamine, CHA\uff09\u4f5c\u4e3a\u4e00\u79cd\u5e38\u89c1\u7684\u6709\u673a\u5316\u5408\u7269\uff0c\u5728\u6709\u673a\u5408\u6210\u9886\u57df\u4e2d\u5177\u6709\u91cd\u8981\u7684\u5e94\u7528\u4ef7\u503c\u3002\u672c\u6587\u7efc\u8ff0\u4e86\u73af\u5df1\u80fa\u5728\u4e0d\u540c\u6709\u673a\u5408\u6210\u53cd\u5e94\u4e2d\u7684\u50ac\u5316\u4f5c\u7528\uff0c\u7279\u522b\u662f\u5176\u5bf9\u53cd\u5e94\u9009\u62e9\u6027\u7684\u5f71\u54cd\u3002\u901a\u8fc7\u8be6\u7ec6\u5206\u6790\u4e0d\u540c\u53cd\u5e94\u6761\u4ef6\u4e0b\u7684\u5b9e\u9a8c\u6570\u636e\uff0c\u63a2\u8ba8\u4e86\u73af\u5df1\u80fa\u4f5c\u4e3a\u50ac\u5316\u5242\u7684\u9009\u62e9\u6027\u548c\u6548\u7387\uff0c\u65e8 &#8230;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[4],"tags":[1306],"_links":{"self":[{"href":"https:\/\/www.dmdee.org\/wp-json\/wp\/v2\/posts\/1803"}],"collection":[{"href":"https:\/\/www.dmdee.org\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.dmdee.org\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.dmdee.org\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.dmdee.org\/wp-json\/wp\/v2\/comments?post=1803"}],"version-history":[{"count":0,"href":"https:\/\/www.dmdee.org\/wp-json\/wp\/v2\/posts\/1803\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.dmdee.org\/wp-json\/wp\/v2\/media?parent=1803"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.dmdee.org\/wp-json\/wp\/v2\/categories?post=1803"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.dmdee.org\/wp-json\/wp\/v2\/tags?post=1803"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}