{"id":237,"date":"2018-07-30T10:31:55","date_gmt":"2018-07-30T02:31:55","guid":{"rendered":"http:\/\/www.dmdee.org\/?p=237"},"modified":"2018-07-30T10:31:55","modified_gmt":"2018-07-30T02:31:55","slug":"dsfdsf","status":"publish","type":"post","link":"https:\/\/www.dmdee.org\/archives\/237","title":{"rendered":"\u5355\u7ec4\u5206\u6c34\u56fa\u5316\u805a\u6c28\u916f\u9632\u6c34\u6d82\u6599\u7684\u7814\u7a76"},"content":{"rendered":"

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1 \u5b9e\u9a8c
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1\uff0e2 \u539f\u6750\u6599\u7684\u9884\u5904\u7406
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1-3 \u5355\u7ec4\u5206\u6c34\u56fa\u5316\u805a\u6c28\u916f\u9632\u6c34\u6d82\u6599\u7684\u5236\u5907
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1\uff0e4 \u6027\u80fd\u6d4b\u8bd5\u4e0e\u7ed3\u6784\u8868\u5f81
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\n\u8bd5\u6837\u7684\u5236\u5907\uff1a\u91c7\u7528\u76f8\u8f6c\u5316\u6cd5\u4e2d\u7684\u5e72\u6cd5\u6210\u819c\u6cd5\uff0c\u5c06\u805a\u6c28\u916f\u914d\u5408\u7269\u6750\u6599\u6d41\u5ef6\u5728\u5e73\u7f6e\u7684\u73bb\u7483\u677f\u4e0a\uff0c\u5728\u6240\u9700\u7684\u6761\u4ef6\u4e0b\u56fa\u5316\u6210\u819c
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2 \u7ed3\u679c\u4e0e\u8ba8\u8bba
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2\uff0e1\u30012 \u73af\u5883\u6e7f\u5ea6\u5bf9\u6750\u6599\u56fa\u5316\u7684\u5f71\u54cd(\u89c1\u88681)<\/p>\n

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2\uff0e1\uff0e3 \u56fa\u5316\u6e29\u5ea6\u5bf9\u6750\u6599\u56fa\u5316\u7684\u5f71\u54cd
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2\uff0e1\uff0e4 \u50ac\u5316\u5242\u542b\u91cf\u5bf9\u6d82\u6599\u56fa\u5316\u7684\u5f71\u54cd
\n\u56fe5 \u662f\u6d82\u819c\u7684\u8868\u5e72\u3001\u5b9e\u5e72\u65f6\u95f4\u4e0e\u50ac\u5316\u5242\u542b\u91cf\u7684\u5173\u7cfb\u3002<\/p>\n

\u7531 \u56fe5 \u53ef\u77e5\uff0c\u968f\u7740\u50ac\u5316\u5242\u542b\u91cf\u7684\u589e\u52a0\uff0c\u52a0\u5feb\u4e86\u56fa\u5316\u53cd\u5e94\uff0c\u6d82\u819c\u7684\u8868\u5e72\u3001\u5b9e\u5e72\u65f6\u95f4\u90fd\u663e\u8457\u7f29\u77ed\uff0c\u4f46\u50ac\u5316\u5242\u542b\u91cf\u8fbe5%\u540e\uff0c\u968f\u7740\u50ac\u5316\u5242\u542b\u91cf\u589e\u52a0\uff0c\u5176\u8d8b\u52bf\u5c31\u4e0d\u592a\u660e\u663e\uff0c\u8d8b\u4e8e\u4e00\u5b9a \u503c\uff0c\u662f\u56e0\u4e3a\u4e00\u5b9a\u91cf\u7684\u6c34\u6027\u805a\u6c28\u916f\u9632\u6c34\u6d82\u6599\u6240\u9700\u50ac\u5316\u5242\u7684\u91cf\u6709\u9650\uff0c\u8fbe\u5230\u4e00\u5b9a\u6d53\u5ea6\u540e\uff0c\u5176\u50ac\u5316\u6548\u679c\u5e76\u4e0d\u660e\u663e\u3002\u56e0\u6b64\uff0c\u50ac\u5316\u5242\u542b\u91cf\u57285%\u5de6\u53f3\u8f83\u597d\u3002
\n2.2 \u56fa\u5316\u7269\u7684\u6d88\u6ce1\u5904\u7406
\n\u5355\u7ec4\u5206\u6c34\u56fa\u5316\u805a\u6c28\u916f\u9632\u6c34\u6d82\u6599\u56fa\u5316\u540e\u51fa\u73b0\u5927\u5c0f\u4e0d\u7b49\u7684\u6c14\u6ce1\uff0c\u5bf9\u6750\u6599\u7684\u9632\u6c34\u6027\u80fd\u548c\u529b\u5b66\u6027\u80fd\u5747\u6709\u4e00\u5b9a\u5f71\u54cd\u3002\u8d77\u6ce1\u7684\u539f\u56e0\u662f\u6210\u819c\u8fc7\u7a0b\u4e2d\u56fa\u5316\u5242\uff08\u6c34\uff09\u4e0e\u9884\u805a\u4f53\u4e2d\u2014NCO \u53cd\u5e94\u65f6\u4ea7\u751f\u7684CO2 \u6c14\u4f53\u4e0d\u80fd\u53ca\u65f6\u4ece\u6d82\u819c\u6563\u9038\uff0c\u6240\u4ee5\u9700\u8981\u8fdb\u884c\u6d88\u6ce1\u5904\u7406\u3002\u4ee5CaO\u3001Ca\uff08OH\uff092 \u4e3a\u4ee3\u8868\u7684\u5316\u5b66\u5438\u6536\u5242\u548c\u4ee5\u7845\u6cb9\u4e3a\u4ee3\u8868\u7684\u7269\u7406\u6d88\u6ce1\u5242\u5747\u53ef\u51cf\u5c11\u6c34\u56fa\u5316\u805a\u6c28\u916f\u9632\u6c34\u6d82\u6599\u4ea7\u751f\u6c14\u6ce1\u7684\u7f3a\u9677[8]\u3002
\n\u56fe6 \u662f\u52a0\u5165\u4e0d\u540c\u6d88\u6ce1\u5242\u524d\u3001\u540e\u6d82\u819c\u7684\u65ad\u53e3\u5f62\u8c8c\u663e\u5fae\u56fe\u3002<\/p>\n

\u7531 \u56fe6 \u53ef\u77e5\uff0c\uff08a\uff09\u3001\uff08c\uff09\u4e2d\u819c\u7684\u65ad\u53e3\u754c\u9762\u6ca1\u6709\u660e\u663e\u7684\u6c14\u5b54\uff0c\u7ed3\u6784\u76f8\u5bf9\u6bd4\u8f83\u81f4\u5bc6\uff0c\uff08b\uff09\u4e2d\u819c\u7684\u65ad\u53e3\u754c\u9762\u6709\u8f83\u660e\u663e\u7684\u6c14\u5b54\u3002\u7ed3\u679c\u8868\u660e\u52a0\u5165Ca\uff08OH\uff092 \u548c\u7845\u6cb9\u6709\u5f88\u597d\u7684\u6d88\u6ce1\u6548\u679c\u3002\u6bd4\u8f83\uff08a\uff09\u3001\uff08c\uff09\u53ef\u77e5\uff0c\u52a0\u5165Ca\uff08OH\uff092 \u7684\u6d82\u819c\u65ad\u53e3\u8868\u9762\u66f4\u89c4\u6574\u3001\u81f4\u5bc6\uff0c\u5e76\u4e14\u52a0\u5165\u6709\u673a\u7845\u6cb9\u540e\uff0c\u6d82\u819c\u529b\u5b66\u6027\u80fd\u6709\u6240\u4e0b\u964d\uff0c\u6240\u4ee5Ca\uff08OH\uff092 \u7684\u6d88\u6ce1\u6548\u679c\u66f4\u597d\u3002
\n2.3 \u5355\u7ec4\u5206\u6c34\u56fa\u5316\u805a\u6c28\u916f\u9632\u6c34\u6d82\u6599\u57fa\u4f53\u7684\u7ea2\u5916\u5149\u8c31\u5206\u6790\uff08\u89c1\u56fe7\uff09<\/p>\n

\u7531\u56fe7 \u4e2d\u7684\u56fe\u8c31a \u53ef\u77e5\uff0c\u57283298 cm-1 \u5de6\u53f3\u6709\u4e2d\u5f3a\u7684\u5438\u6536\u5cf0\u6ce2\u6570\uff0c\u4e3a\u2014NHCO\u4e2dNH \u7684\u987a\u5f0f\u4f38\u5c55\u632f\u52a8\uff0c2970 cm-1 \u548c2870cm-1 \u6709\u5f3a\u5cf0\uff0c\u4e3a\u2014CH2\u3001\u2014CH3 \u7684\u4f38\u5c55\u632f\u52a8\uff1b2270 cm-1 \u5de6\u53f3\u6709\u5f3a\u5cf0\uff0c\u4e3a\u2014NCO\u7684\u7279\u5f81\u5438\u6536\u5cf0\uff1b1715\uff5e1750 cm-1 \u4e3a\u2014C=O \u57fa\u7684\u5438\u6536\u5cf0\uff0c1597 cm-1 \u4e3a\u73afC=C \u9aa8\u67b6\u4f38\u5c55\u632f\u52a8\uff0c1225\uff5e1235 cm-1 \u4e3a\u805a\u916fC\u2014O\u4f38\u5c55\u6216\u2014OH \u7684\u53d8\u5f62\u632f\u52a8\uff0c1060\uff5e1150 cm-1 \u6709\u8f83\u5bbd\u7684\u5438\u6536\u5cf0\uff0c\u4e3aC\u2014O\u2014C\uff08\u8102\u80aa\u65cf\u919a\uff09\u5438\u6536\u5cf0\uff0c\u57281405\uff5e1600 cm-1 \u9644\u8fd1\u6709\u73af\u7279\u5f81\u5cf0\u3002\u6bd4\u8f83\u56fe\u8c31a\u3001b \u53d1\u73b0\uff0cb \u4e2d\u2014NCO\u7684\u7279\u5f81\u5438\u6536\u5cf0\u51e0\u4e4e\u6d88\u5931\uff0c\u800c\u4e9a\u80fa\u57fa\u2014NH\u2014\u7684\u7279\u5f81\u5cf03304 cm-1 \u5374\u589e\u5f3a\uff0c\u8fd9\u662f\u56e0\u4e3a\u56fa\u5316\u8fc7\u7a0b\u4e2d\u53d1\u751f\u4e86\u4ea4\u8054\u53cd\u5e94\uff0c\u9884\u805a\u4f53\u4e2d\u7684\u6d3b\u6027\u57fa\u56e2\u5f02\u6c30\u9178\u6839\u2014NCO\u548c\u2014OH \u53d1\u751f\u5316\u5b66\u53cd\u5e94\u751f\u6210\u2014NHCOO\u3002
\n3 \u7ed3\u8bba
\n\uff081\uff09\u8be5\u5355\u7ec4\u5206\u6c34\u56fa\u5316\u805a\u6c28\u916f\u9632\u6c34\u6d82\u6599\u80fd\u591f\u5728- 14\uff5e40 \u2103\u4e4b\u95f4\u6210\u819c\uff1b\u8868\u5e72\u65f6\u95f4\u5c0f\u4e8e4 h\uff0c\u5b9e\u5e72\u65f6\u95f4\u4e0d\u5927\u4e8e8 h\uff1b\u6210\u819c\u540e\u819c\u8868\u9762\u8f83\u5149\u6ed1\u3002
\n\uff082\uff09\u65bd\u5de5\u65f6\uff0c\u52a0\u6c34\u91cf\u572830%\u5de6\u53f3\u65f6\uff0c\u6c34\u56fa\u5316\u805a\u6c28\u916f\u6750\u6599\u6d82\u819c\u7684\u529b\u5b66\u6027\u80fd\u8f83\u4f18\uff0c\u800c\u4e14\u56fa\u5316\u65f6\u95f4\u4e5f\u9002\u4e2d\u3002
\n\uff083\uff09\u6e7f\u5ea6\u589e\u5927\uff0c\u6d82\u819c\u56fa\u5316\u65f6\u95f4\u7f29\u77ed\uff0c\u4f46\u6210\u819c\u7269\u8868\u9762\u89c4\u6574\u6027\u4e0b\u964d\uff0c\u56fa\u5316\u65f6\u6e7f\u5ea6\u9002\u4e2d\u8f83\u597d\u3002
\n\uff084\uff09\u52a0\u5165\u50ac\u5316\u5242\uff0c\u80fd\u52a0\u5feb\u56fa\u5316\u901f\u5ea6\uff0c\u542b\u91cf\u57285%\u5b9c\u3002
\n\uff085\uff09Ca\uff08OH\uff092 \u548c\u7845\u6cb9\u90fd\u6709\u8f83\u597d\u7684\u6d88\u6ce1\u6548\u679c\uff0c\u4f46Ca\uff08OH\uff092\u6548\u679c\u66f4\u597d\u3002
\n\u53c2\u8003\u6587\u732e:
\n[1] \u674e\u7ecd\u96c4\uff0c\u6731\u5415\u6c11.\u805a\u6c28\u916f\u6811\u8102[M].\u5357\u4eac\uff1a\u6c5f\u82cf\u79d1\u5b66\u6280\u672f\u51fa\u7248\u793e\uff0c1992.
\n[2] \u5218\u610f\uff0c\u5f20\u529b\uff0c\u5218\u656c\u82b9\uff0c\u7b49.\u805a\u6c28\u916f\u6d82\u6599\u7684\u7814\u7a76\u8fdb\u5c55[J].\u8fbd\u5b81\u5316\u5de5\uff0c2002\uff0c31\uff083\uff09\uff1a101- 102.
\n[3] Gunter O.Polyurethane Handbook [M].New York\uff1aHanser Publi -shers.1985.
\n[4] \u97e9\u559c\u6797.\u5355\u7ec4\u5206\u6e7f\u56fa\u5316\u5f69\u8272\u805a\u6c28\u916f\u9632\u6c34\u6d82\u6599[J].\u5316\u5b66\u5efa\u6750\uff0c1997\uff0c3\uff084\uff09\uff1a36- 40.
\n[5] Saunder J H\uff0cFrisch K C.Polyurethanes Part I Chemistry [P]. NewYork\uff1aJohn Wiley & Sons Inc.1962.
\n[6] \u5218\u56fd\u6770\uff0c\u803f\u8000\u5b97.\u6d82\u6599\u5e94\u7528\u79d1\u5b66\u4e0e\u5de5\u827a\u5b66[M].\u5317\u4eac\uff1a\u4e2d\u56fd\u8f7b\u5de5\u4e1a\u51fa\u7248\u793e.1999.
\n[7] \u9a6c\u5efa\u4e2d\uff0c\u5170\u4e91\u519b\uff0c\u738b\u5229\u6c11\uff0c\u7b49.\u5236\u9769\u6574\u9970\u6750\u6599\u5316\u5b66[M].\u5317\u4eac\uff1a\u4e2d\u56fd\u8f7b\u5de5\u4e1a\u51fa\u7248\u793e\uff0c1998\uff1a464.
\n[8] \u53f2\u7acb\u5e73\uff0c\u5b54\u5fd7\u5143\uff0c\u4f55\u5e86\u8fea\uff0c\u7b49.\u6c34\u6027\u805a\u6c28\u916f\u6728\u5668\u6f06\u4e2d\u6d88\u6ce1\u5242\u7684\u9009\u7528[J].\u73b0\u4ee3\u6d82\u6599\u4e0e\u6d82\u88c5\uff0c2003\uff086\uff09\uff1a46- 48.<\/p>\n","protected":false},"excerpt":{"rendered":"

\u5355\u7ec4\u5206\u6c34\u56fa\u5316\u805a\u6c28\u916f\u9632\u6c34\u6d82\u6599\u7684\u7814\u7a76 \u805a\u6c28\u916f(PU)\u6d82\u6599\u56fa\u5316\u540e\u6d82\u819c\u5177\u6709\u826f\u597d\u7684\u8010\u78e8\u6027\u3001\u8010\u8150\u8680\u6027\u3001\u8010\u5316\u5b66\u54c1\u6027\u4ee5\u53ca\u786c\u5ea6\u5927\u3001\u5f39\u6027\u9ad8\u7b49\u4f18\u70b9\u3002\u76ee\u524d\uff0c\u5e02\u552e\u7684\u805a\u6c28\u916f\u9632\u6c34\u6d82\u6599\u4e3b\u8981\u662f\u53cc\u7ec4\u5206\uff0c\u7531A\u3001B\u4e24\u7ec4 \u5206\u6784\u6210\uff0c\u4f7f\u7528\u65f6\u4e24\u7ec4\u5206\u987b\u4e25\u683c\u6309\u89c4\u5b9a\u6bd4\u4f8b\u79f0\u91cf\u3001\u6df7\u5408\uff0c\u65bd\u5de5\u4e0d\u65b9\u4fbf\uff0c\u5176\u4e2d\u542b\u6709\u5927\u91cf\u7684\u6709\u673a\u6eb6\u5242\uff0c\u5e76\u4e14\u5e38\u7528\u80fa\u7c7b\u56fa\u5316\u5242(\u5982MOCA)\u4f5cB\u7ec4\u5206\u6269\u94fe\u5242\uff0c\u8fd9\u4e9b\u7269\u8d28 …<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[4],"tags":[39],"_links":{"self":[{"href":"https:\/\/www.dmdee.org\/wp-json\/wp\/v2\/posts\/237"}],"collection":[{"href":"https:\/\/www.dmdee.org\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.dmdee.org\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.dmdee.org\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.dmdee.org\/wp-json\/wp\/v2\/comments?post=237"}],"version-history":[{"count":1,"href":"https:\/\/www.dmdee.org\/wp-json\/wp\/v2\/posts\/237\/revisions"}],"predecessor-version":[{"id":238,"href":"https:\/\/www.dmdee.org\/wp-json\/wp\/v2\/posts\/237\/revisions\/238"}],"wp:attachment":[{"href":"https:\/\/www.dmdee.org\/wp-json\/wp\/v2\/media?parent=237"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.dmdee.org\/wp-json\/wp\/v2\/categories?post=237"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.dmdee.org\/wp-json\/wp\/v2\/tags?post=237"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}